Comparison of the Main Properties of DOTP, Citric Acid, and Citrate Esters: Flexibility and Softness: DOTP: Excellent, can produce soft and durable PVC products. Citric Acid: Negligible effect; may harden or degrade the polymer. Citrate Esters: Good, but less effective than DOTP at the same addition level. Thermal Stability: DOTP: High, stable below 200°C, suitable for high-temperature processing. Citric Acid: Poor; decomposes at PVC processing temperatures. Citrate Esters: Moderate, less stable
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SOLVED: 4-6BDibutyl phthalate (DBP) plasticizer; has a potential market of 12 million Ib/yr (AIChE Student Contest Problem) and is to be produced by the reaction of n-butanol with monobutyl phthalate (MBP). The reaction follows an elementary rate law and is catalyzed by H2SO4 (Figure P4-6B). A stream containing MBP and butanol is to be mixed with the H2SO4 catalyst immediately before the stream enters the reactor. The concentration of MBP in the stream entering the reactor is 0.2 Ib mol/ft^3, an
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